• 水中有机物监测精密度控制水平研究
    《中国测试》杂志夏 新1, 米方卓1, 吴晓凤1, 李 娟2, 池 靖1

    夏  新1, 米方卓1, 吴晓凤1, 李  娟2, 池  靖1
    (1. 中国环境监测总站,北京 100012; 2. 江苏省环境监测中心,江苏 南京 210036)
    摘  要:针对水中51种有机物监测的精密度控制水平,提出两种概率(γ=0.90,P=0.90;γ=0.95,P=0.95)下的质量控制指标。研究结果表明:51种有机物的空白样品加标回收率测定相对偏差可控制在15%以内,实际样品和实际样品加标回收率的相对偏差可控制在20%以内,基质在一定程度上影响精密度的测定。
    关键词:有机物;精密度;质量控制;相对偏差
    中图分类号:X830.5;X832;TQ21;TQ016.1        文献标志码:A        文章编号:1674-5124(2013)04-0005-05
    Relative deviation analysis of organic compounds in the water
    XIA Xin1, MI Fang-zhuo1, WU Xiao-feng1, LI Juan2, CHI Jing1
    (1. China National Environmental Monitoring Center,Beijing 100012,China;
    2. Jiangsu Environmental Monitoring Center,Nanjing 210036,China)
    Abstract: Through analyzing the monitoring data, the authors studied the relative deviation of 51 organic compounds in water, and put forward the quality control (QC) index under two kinds of probabilities (γ=0.90, P=0.90; γ=0.95, P=0.95) to provide the QC index for the people in the monitoring area. Studies indicate that the relative deviation of the actual samples and the recoveries of actual samples are higher than those of the blank samples. The relative deviation of the blank sample recovery could be controlled within 15%, which could be extended appropriately. The relative deviation of the actual samples and the actual sample recovery could be controlled within 20%.
    Key words: organic compound; relative deviation; quality control; relative deviation
     
     
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